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Why Calcium Chloride?

The Facts About Calcium Chloride - OxyChem Calcium Chloride

The Facts About Calcium Chloride

Calcium chloride (CaCl2) is one of nature’s uncommon wonders. It’s a specialty salt with unique properties that improves driving and pedestrian safety, suppresses dust from the air we breathe, and enhances the performance of products and processes that contribute to the supply of energy, food, and other essentials of life.

OxyChem’s calcium chloride is refined from natural brines found in sandstone formations beneath the earth in a non-synthetic process, avoiding the need for reactions with chemicals used in other CaCl2 manufacturing processes.

The Magic of Moisture and Heat

Calcium chloride has three unique and highly effective performance properties:

  1. Hygroscopic – attracts moisture from its surroundings.
  2. Deliquescent – absorbs enough moisture to convert to liquid brine from solid form.
  3. Exothermic – releases heat when its solid form is dissolved in water.

Calcium chloride is an exceptional ice melter because it quickly and easily dissolves into a brine solution, while releasing heat to speed up the ice melting process. It is also a highly effective dust suppressant and stabilizing agent in unpaved roads since it attracts water from the air binding gravel particles together.

 

Calcium Chloride for Melting Ice

Effective ice melting depends on selecting a deicer capable of melting ice quickly and efficiently under winter temperature conditions typical in your area, and then applying it properly. Several performance characteristics should guide the selection of an ice melter, but two are particularly important:

  • Will the deicer be effective across all temperatures you are likely to experience?
  • How quickly will the deicer melt ice to minimize pedestrian exposure to potentially dangerous conditions?

Superior Temperature Performance

When the goal is keeping sidewalks safe under all conditions, calcium chloride stands apart from other options as it maintains ice melting power down to -25°F (-32°C). In contrast, other deicers like rock salt, potassium chloride and calcium magnesium acetate begin losing effectiveness between 25°F (-4°C) and 0°F (-18°C). 

Advanced Melting Speed

Calcium chloride’s hygroscopic properties means that it melts ice faster than other deicers. Calcium chloride attracts moisture from the surface and the surrounding air, forming an ice-melting brine faster that lowers the freezing point of water and gives melting action a faster start. 

While most other deicers depend on their surroundings for heat, calcium chloride generates heat as it dissolves to form ice melting brine. This heat release is especially important during cold weather when other deicers lose effectiveness.

Shape Matters

Round-shaped ice melters like PELADOW® Calcium Chloride Pellets can bore through ice quickly to penetrate and break ice’s bond with underlying pavement. 

Flat or crystal-shaped ice melters like DOWFLAKE® Xtra or COMBOTHERM® spread out over the surface of ice as they dissolve.

Better than Blends

Avoid being misled by performance claims touted by blends that are little more than attractively packaged rock salt containing insignificant amounts of higher-performance ice melter. Always ask for a formal statement from the manufacturer or distributor identifying the precise product ingredients by percentage. In blends containing calcium chloride and rock salt, look for at least 20% calcium chloride content to see an appreciable increase in performance over rock salt alone.

Compared to Magnesium Chloride

PELADOW® Calcium Chloride Pellets can melt more snow and ice with LESS TIME, LESS COST and LESS WASTE.

For more details see MELT RESPONSIBLY® - OxyChem Calcium Chloride

Calcium chloride and magnesium chloride are both salt compounds, solids at room temperature, highly soluble in water, and used for melting snow and ice. But there are important performance differences that should be considered when choosing between the two.

PELADOW® Calcium Chloride vs. Magnesium Chloride

Property

PELADOW® Calcium Chloride (CaCl2)

Magnesium Chloride (MgCl2)

Exothermic

Yes

Yes

Lowest Effective Temperature

-25°F (-32°C)

0°F (-18°C)

Ice Melted in 30 Minutes (per lb of deicer) at 20°F

5.7 lb

3.2 lb

Percent Active Ingredient

90%

47% Solid magnesium chloride 53% water by weight

Quantity to Melt 1000 sq. ft. of Ice

30 lbs.

50 lbs.

Temperature Rise of a Gallon of Water with 1 lb. of Product

>30°F (17°C)

~3ºF (-16ºC)

Environmental Impact

PELADOW® uses 40% less product to melt the same area as magnesium chloride in 30 minutes at 20⁰F. Because of this, PELADOW® introduces up to 15% less chlorides into the environment and causes less turfgrass damage. Learn more at MeltResponsibly.com.

Product Origin

Manufactured in the U.S.A and readily available in strategic sourcing locations across North America.

Some is domestically produced and available in the western U.S. Most is imported with 6-8 weeks lead times during peak winter demand.

PELADOW® Calcium Chloride vs. Magnesium Chloride
Exothermic

PELADOW® Calcium Chloride (CaCl2)

Yes

Magnesium Chloride (MgCl2)

Yes

Lowest Effective Temperature

PELADOW® Calcium Chloride (CaCl2)

-25°F (-32°C)

Magnesium Chloride (MgCl2)

0°F (-18°C)

Ice Melted in 30 Minutes (per lb of deicer) at 20°F

PELADOW® Calcium Chloride (CaCl2)

5.7 lb

Magnesium Chloride (MgCl2)

3.2 lb

Percent Active Ingredient

PELADOW® Calcium Chloride (CaCl2)

90%

Magnesium Chloride (MgCl2)

47% Solid magnesium chloride 53% water by weight

Quantity to Melt 1000 sq. ft. of Ice

PELADOW® Calcium Chloride (CaCl2)

30 lbs.

Magnesium Chloride (MgCl2)

50 lbs.

Temperature Rise of a Gallon of Water with 1 lb. of Product

PELADOW® Calcium Chloride (CaCl2)

>30°F (17°C)

Magnesium Chloride (MgCl2)

~3ºF (-16ºC)

Environmental Impact

PELADOW® Calcium Chloride (CaCl2)

PELADOW® uses 40% less product to melt the same area as magnesium chloride in 30 minutes at 20⁰F. Because of this, PELADOW® introduces up to 15% less chlorides into the environment and causes less turfgrass damage. Learn more at MeltResponsibly.com.

Product Origin

PELADOW® Calcium Chloride (CaCl2)

Manufactured in the U.S.A and readily available in strategic sourcing locations across North America.

Magnesium Chloride (MgCl2)

Some is domestically produced and available in the western U.S. Most is imported with 6-8 weeks lead times during peak winter demand.

Recommended Products

Calcium Chloride for Dust Control

Effective dust prevention measures are essential to preserving the drivability and durability of unpaved roads, minimizing impact on the natural environment, and protecting the health, safety, property, and quality of life of those who live on, work near, or travel on gravel roads.  

Calcium chloride is a hygroscopic salt that draws moisture from the air to form a solution in road gravel that keeps road surfaces constantly damp—even in hot, dry conditions. The moisture helps to bind particles together to create a hard and compact road surface. Because it penetrates several inches into the road base, calcium chloride contributes to overall road surface stability. It also depresses the freezing point of the moisture in the road surface to help minimize frost heave damage in the winter.

Compared to Magnesium Chloride and Mineral Well Brines

Three frequently used dust suppressants are calcium chloride, magnesium chloride, and mineral well brines. All contain hygroscopic materials that draw moisture from the air providing extended dust suppression by forming a solution in road gravel keeping road surfaces constantly damp. However, the performance differences should be noted and considered before choosing which to use.

LIQUIDOW® Calcium Chloride Solution vs. Magnesium Chloride vs. Mineral Well Brines

Property

LIQUIDOW® Calcium Chloride Solution (CaCl2)

Magnesium Chloride (MgCl2)

Mineral Well Brines

How it Works

CaCl2 draws moisture from the air to form a solution that keeps road surfaces constantly damp. The moisture helps to bind particles together to create a hard and compact road surface. 

MgCl2 draws moisture from the air to form a solution that keeps road surfaces constantly damp. The moisture helps to bind particles together to create a hard and compact road surface.

Mineral well brines contain sodium chloride (NaCl), CaCl2, and MgCl2.

 

The CaCl2 and MgCl2 in the brine draw moisture from the air to form a solution that keeps road surfaces constantly damp.

 

NaCl only draws moisture at very high humidities.

Typical Application Concentrations

United States – 38%
Canada – 35%

30%

Dependent on brine source.

 

CaCl2 and MgCl2 concentrations are less than that of LIQUIDOW® solutions.

 

NaCl concentrations are much higher than that of LIQUIDOW® solutions.

Typical Application Rates

0.20 – 0.35 gal/yd2
0.9 – 1.6 L/m2

0.30 – 0.50 gal/yd2
1.4 – 2.3 L/m2

Typically, much higher than LIQUIDOW® solution application rates.

 

Dependent on CaCl2 and MgCl2 concentrations.

Performance in Hot, Dry Conditions

Under hot, dry conditions, CaCl2 remains a liquid, continuing to help control dust.

Under very hot, dry conditions, MgCl2 may not remain a liquid, and therefore may have lower dust suppression capabilities in these conditions.

Under very hot, dry conditions, MgCl2 and NaCl may not remain a liquid, and therefore may have lower dust suppression capabilities in these conditions.

Environmental Impact

When following proper handling and application procedures, including using recommended application rates, environmental concerns related to CaCl2 can be effectively managed.

When following proper handling and application procedures, including using recommended application rates, environmental concerns related to MgCl2 can be effectively managed.

By using more brine to achieve dust control, the amount of dust suppressant material introduced into the environment is increased, potentially increasing impact. In some jurisdictions, regulations may require permits for the use of well head brine to treat roadways. What’s more, the relatively high concentrations of NaCl in mineral well brines can be detrimental to soil structure and soil permeability, posing additional environmental risk.

LIQUIDOW® Calcium Chloride Solution vs. Magnesium Chloride vs. Mineral Well Brines
How it Works

LIQUIDOW® Calcium Chloride Solution (CaCl2)

CaCl2 draws moisture from the air to form a solution that keeps road surfaces constantly damp. The moisture helps to bind particles together to create a hard and compact road surface. 

Magnesium Chloride (MgCl2)

MgCl2 draws moisture from the air to form a solution that keeps road surfaces constantly damp. The moisture helps to bind particles together to create a hard and compact road surface.

Mineral Well Brines

Mineral well brines contain sodium chloride (NaCl), CaCl2, and MgCl2.

 

The CaCl2 and MgCl2 in the brine draw moisture from the air to form a solution that keeps road surfaces constantly damp.

 

NaCl only draws moisture at very high humidities.

Typical Application Concentrations

LIQUIDOW® Calcium Chloride Solution (CaCl2)

United States – 38%
Canada – 35%

Magnesium Chloride (MgCl2)

30%

Mineral Well Brines

Dependent on brine source.

 

CaCl2 and MgCl2 concentrations are less than that of LIQUIDOW® solutions.

 

NaCl concentrations are much higher than that of LIQUIDOW® solutions.

Typical Application Rates

LIQUIDOW® Calcium Chloride Solution (CaCl2)

0.20 – 0.35 gal/yd2
0.9 – 1.6 L/m2

Magnesium Chloride (MgCl2)

0.30 – 0.50 gal/yd2
1.4 – 2.3 L/m2

Mineral Well Brines

Typically, much higher than LIQUIDOW® solution application rates.

 

Dependent on CaCl2 and MgCl2 concentrations.

Performance in Hot, Dry Conditions

LIQUIDOW® Calcium Chloride Solution (CaCl2)

Under hot, dry conditions, CaCl2 remains a liquid, continuing to help control dust.

Magnesium Chloride (MgCl2)

Under very hot, dry conditions, MgCl2 may not remain a liquid, and therefore may have lower dust suppression capabilities in these conditions.

Mineral Well Brines

Under very hot, dry conditions, MgCl2 and NaCl may not remain a liquid, and therefore may have lower dust suppression capabilities in these conditions.

Environmental Impact

LIQUIDOW® Calcium Chloride Solution (CaCl2)

When following proper handling and application procedures, including using recommended application rates, environmental concerns related to CaCl2 can be effectively managed.

Magnesium Chloride (MgCl2)

When following proper handling and application procedures, including using recommended application rates, environmental concerns related to MgCl2 can be effectively managed.

Mineral Well Brines

By using more brine to achieve dust control, the amount of dust suppressant material introduced into the environment is increased, potentially increasing impact. In some jurisdictions, regulations may require permits for the use of well head brine to treat roadways. What’s more, the relatively high concentrations of NaCl in mineral well brines can be detrimental to soil structure and soil permeability, posing additional environmental risk.

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